Hi Tony & welcome to Loaches Online.
As this is your first post on the forum, I have no idea what your level of fishkeeping experience is, and without wanting to offend you (or others), I wouldn't recommend trying to lower the pH of your clown loach aquarium to this sort of level unless you have a lot of fishkeeping experience.
The pH in our tank was always maintained around 6.0 with a general hardness level of 5-6dH. We use solely RO water with a low level of remineralisation (Tropic Marin Remineral Freshwater powder) and very large amount of big bogwood pieces. The tank is extremely well filtered, but the stocking level is high, so the organic load is pretty high. Frequent partial water changes keep the nitrate level below 40ppm (in fact it is usually much lower). Because of all these factors, we found that the pH, over a period of about 6-12 months, gradually dropped. As we were not observing any negative effects on the fish or their behaviour, we decided not to interfere at that point, and subsequently, it dropped below 4. The lowest it got to at one stage was 3.7. However, once it was this low, we found that our Green Mascara Barbs (
Puntius filamentosus) stopped spawning, and as there has been virtually nothing documented on keeping clown loaches in these conditions long-term, we were not 100% sure we should be keeping it there. The fish did all look very vibrant and healthy though.
It
must be taken into consideration that as the pH is dropped low, the bacteria in the filtration may initially die off and so you have to be very vigilant for ammonia spikes. Although we found that when the pH got to around 5.5 we saw a moderate level of ammonia, the fact that we were doing daily water changes coupled with the fact that at this level of pH you would need a massive amount of ammonia present for it to be toxic to the fish (ammonia toxicity decreases as the pH decreases), meant that this wasn't a problem.
However, this could pose a threat to the fish if your pH was swinging about a lot more, or if you chose to suddenly increase the pH back to it's usual neutral(ish) position. For example, if you were using your main tank in a breeding attempt, and the pH was lowered to say 4-5, this change would kill most (if not all) the bacteria in the filter, then if the pH was unstable or if it was brought back up towards neutral too quickly so that the bacteria did not have time to re-establish, you could have major losses.
This is why it needs careful thinking about and constant vigilance. When we decided to increase our pH back up to 6.0-6.5, we added a very small amount of Aragonite (calcium carbonate gravel) to one of our external filters. We started off with about 10% of what we ended up needing in total to raise the pH very gradually (over some months) and kept it stable. It took a good 8 weeks or so to do this, initially also adding a small amount of zeolite, and there was never any ammonia spike.
If you wish to lower the pH without using RO water, I would firstly suggest using peat. If the tank is so big (I have no idea what size your tank is) that using peat isn't viable - and if you are confident in what you are doing - it is possible to use hydrochloric acid. However, I am not going to advise you to do this on here as I would not want to be held responsible for you or anyone else reading this if you were to lose fish or injure yourself (HCl being highly corrosive and dangerous to use).
Never use HCl
directly in the tank.
Due to Colin's recent success, and subsequent conversations between him & I, I am now confident that the low pH & hardness level is the way to go. I am currently in the process of removing some of the Aragonite from the filters in order to begin dropping the pH again. However, if a real attempt at spawning is to be made, I will have to try and acquire a separate decent sized aquarium to try this in, as I believe that the presence of too many individuals may have hampered my previous efforts.
Hope this helps, and although it is obvious - be very careful with altering water parameters so drastically, particularly where precious XL clowns are concerned.
Emma